By Bin Liu, Guillermo C. Bazan
Chapter 1 layout and Synthesis of Conjugated Polyelectrolytes (pages 1–64): Kan?Yi Pu, Guan Wang and Prof. Bin Liu
Chapter 2 All?Conjugated Rod–Rod Diblock Copolymers Containing Conjugated Polyelectrolyte Blocks (pages 65–89): Ullrich Scherf, Rachel C. Evans, Andrea Gutacker and Prof. Guillermo C. Bazan
Chapter three Ionically Functionalized Polyacetylenes (pages 91–126): Stephen G. Robinson and Mark C. Lonergan
Chapter four Aggregation houses of Conjugated Polyelectrolytes (pages 127–167): Hugh D. Burrows, Matti Knaapila, Sofia M. Fonseca and Telma Costa
Chapter five Sensing through Quenching of Conjugated Polyelectrolyte Fluorescence (pages 169–200): Danlu Wu, Jie Yang, Fude Feng and Kirk S. Schanze
Chapter 6 Sensing functions through power move from Conjugated Polyelectrolytes (pages 201–229): Fengting Lv, Shu Wang and Prof. Guillermo C. Bazan
Chapter 7 Sensing through Conformational alterations of Conjugated Polythiophenes (pages 231–261): Even J. Lemieux and Mario Leclerc
Chapter eight Conjugated Polyelectrolyte?Based Biocide purposes (pages 263–294): Thomas S. Corbitt, Eunkyung Ji, Ying Wang, Anand Parthasarathy, Kristin N. Wilde, Eric H. Hill, Dimitri Dascier, Heather E. Canavan, Eva Y. Chi, Kirk S. Schanze and David G. Whitten
Chapter nine Conjugated Polyelectrolyte?Based Imaging and tracking of Protein Aggregation (pages 295–314): okay. Peter R. Nilsson and consistent with Hammarstrom
Chapter 10 cost Injection Mechanism in PLEDs and cost shipping in Conjugated Polyelectrolytes (pages 315–344): Peter Zalar and Thuc?Quyen Nguyen
Chapter eleven natural Optoelectronic units Containing Water/Alcohol?Soluble Conjugated Polymers and Conjugated Polyelectrolytes* (pages 345–388): Sujun Hu, Chengmei Zhong, Hongbin Wu and Yong Cao
Chapter 12 Optical techniques in Conjugated Polyelectrolytes Dependence on Chain Conformation and movie Morphology (pages 389–410): Giuseppina speed and Richard good friend
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Extra info for Conjugated Polyelectrolytes: Fundamentals and Applications
14 N N Synthesis of cationic poly(p-phenylene)s (P34–P38). 1 Cationic Poly(ﬂuorene)s The ﬁrst cationic poly(ﬂuorene) was based on the key monomer of 2,5-bis[3-(N,N-dimethylamino)-1-oxapropyl)-1,4-dibromobenzene] (34) . 16, 34 was synthesized via etheriﬁcation of dibromohydroquinone (29) with 2-chlorotrimethylamine hydrochloride and potassium carbonate in acetone. Subsequently, the Suzuki polymerization between 34 and 2,7-bis-9,9 -dihexylﬂuorenyl-(1,3,2-dioxaborinane) gave the neutral polymer P42.
2 Poly(arylene)s 19 O B O O Br Br t-BuLi/pentane O B O O B O Br(H2C)6 Br(H2C)6 (CH2)6Br (CH2)6Br Br R BrMe3N(H2C)6 R (CH2)6NMe3Br Synthesis of cationic polyﬂuorenes (P59a–d). 22 (i) Pd(PPh3)4/Na2CO3 toluene/H2O BrMe3N(H2C)6 (ii) THF/H2O/NMe3 O O OCH3 Br P62a: R = OCH3 P62b: R = P62c: R = n (CH2)6NMe3Br O O O R R O O NMe3Br OCH3 OCH3 Synthesis of cationic polyﬂuorenes (P60), (P61), and (P62a–c). orbital, respectively. These CPEs have been used for sensor applications as described in Chapter 6. The availability of 43 allows the facile synthesis of a series of cationic polyﬂuorenes with different side chains [28, 109].
20). This was followed by trimethylamine treatment to afford P57 with >95% degree of quaternization. Poly(ﬂuorene-co-phenylene)s (P57a–f) with different amount of meta-phenyl units have been synthesized to adapt to the secondary structure of biomolecules. Cationic poly(ﬂuorene-co-thiophene) (P58) was synthesized similarly from 9,9-bis(6-bromohexyl)-2,7-diiodoﬂuorene (42) and 2,5-bis (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene followed by trimethylamine treatment . 21) . 2 Poly(arylene)s 19 O B O O Br Br t-BuLi/pentane O B O O B O Br(H2C)6 Br(H2C)6 (CH2)6Br (CH2)6Br Br R BrMe3N(H2C)6 R (CH2)6NMe3Br Synthesis of cationic polyﬂuorenes (P59a–d).
Conjugated Polyelectrolytes: Fundamentals and Applications by Bin Liu, Guillermo C. Bazan