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By R. R. Dogonadze, A. M. Kuznetsov (auth.), Brian E. Conway, John O’M. Bockris, Ernest Yeager, Shahed U. M. Khan, Ralph E. White (eds.)

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ISBN-13: 9781461335849

ISBN-10: 1461335868

ISBN-13: 9781461335863

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Additional resources for Comprehensive Treatise of Electrochemistry: Volume 7 Kinetics and Mechanisms of Electrode Processes

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Kuznetsov, and V. G. Levich, Electrochim. Acta 13, 1025 (1968). 34. J. Jortner, J. Chem. Phys. 64, 4860 (1976). 35. R. R. Dogonadze and A. M. Kuznetsov, in Itogo Nauki i Techniki, Ser. Phys. , Kinetics, Vol. 2, ed VINITI of the USSR (Russian edition), Moscow (1973). 36. R. R. Dogonadze and A. M. Kuznetsov, Prog. Surf. Sci. 6,1 (1975). 37. R. A. Marcus, J. Phys. Chem. 72, 891 (1968). 38. V. G. Levich, R. R. Dogonadze, E. D. German, A. M. Kuznetsov, and Yu. I. Kharkats, Electrochim. Acta 15,353 (1970).

Phys. 24, 966, 979 (1956); 26, 867 (1957). 16. R. A. Marcus, Can. J. Chem. 37, 155 (1959). 17. R. A. Marcus, in Transactions of the Symposium on Electrode Processes, E. Yeager, ed. John Wiley and Sons, New York (1961), p. 239. 18. R. A. Marcus, J. Phys. Chem. 67, 853, 2889 (1963). 19. R. A. Marcus, J. Chem. Phys. 38, 1335, 1858 (1963); 39,1734 (1963); 41, 603, 2624 (1964); 43,679 (1965). 20. N. S. Hush, J. Chem. Phys. 28, 962 (1958); Trans. Faraday Soc. 57, 557 (1961). 21. H. Gerischer, Z. Phys.

Therefore, the activation energy is determined mainly by the solvent reorganization energy and the reaction free energy. The profile of the potential energy surfaces along the proton coordinate determines mainly the transmission coefficient. 2. Partly Adiabatic and Entirely Adiabatic Reactions In the normal region, for not too large proton jump distances, the term in Eq. (46) corresponding to the unexcited vibrational proton states is dominant (m = n = 0). It may be written in the form WOO _ if - Weff 21T nonad Kep nonad K ep - exp Ke S (_ E~Onad) kT (48) (49) where E~onad may be easily found by comparing Eqs.

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Comprehensive Treatise of Electrochemistry: Volume 7 Kinetics and Mechanisms of Electrode Processes by R. R. Dogonadze, A. M. Kuznetsov (auth.), Brian E. Conway, John O’M. Bockris, Ernest Yeager, Shahed U. M. Khan, Ralph E. White (eds.)


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