Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, Phil N.'s Chemically Modified Electrodes (Advances in Electrochemical PDF

By Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, Phil N. Ross

ISBN-10: 3527314202

ISBN-13: 9783527314201

With contributions from a world crew of specialist authors, this e-book contains the most recent tendencies in tailoring interfacial houses electrochemically. The chapters disguise a number of natural and inorganic compounds, with functions starting from electrochemistry to nanotechnology and biology.
Of curiosity to actual, floor and electrochemists, fabrics scientists and physicists.

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Extra info for Chemically Modified Electrodes (Advances in Electrochemical Sciences and Engineering)

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3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications The final aspect of the electrode design in the work by Hess et al. 25 Scheme for the use of molecular wires to sense DNA hybridization where a capture DNA is used to attract the target DNA and then a signal DNA with ferrocene labels is hybridized to signal the hybridization event. (Reprinted from [138] J. Mol. Diagn. ) electronics. 25). The self-assembled monolayer used to modify the electrode to give it selectivity for DNA comprised three components.

It is noteworthy that an almost identical rate constant was reported by Zhao et al. [95] using nanotube-modified electrodes prepared in a very similar way. Work on the nanostructuring of electrodes with carbon nanotubes by Gooding and coworkers [96, 97] has demonstrated that superior electrochemical performance can be achieved with carbon nanotubes that are vertically aligned compared with being j29 j 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications 30 randomly dispersed.

The gold surface was then modified with the alkanethiol cysteamine. An alumina membrane was placed onto this cysteamine-modified surface and gold was then electrodeposited. Upon the removal of the alumina membrane in sodium hydroxide, a nanostructured electrode of gold nanotubes was produced. 6 times higher electroactive surface area than that of the unmodified, flat gold electrode. 13 Stepwise synthesis of direct gold sputtering onto alumina membrane to produce nanostructures. (Reprinted with permission from Ref.

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Chemically Modified Electrodes (Advances in Electrochemical Sciences and Engineering) by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, Phil N. Ross

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